科学研究
 

绿色化工与工业催化科研团队

发布日期:2022-04-27   发布人:   浏览次数:;

 

团队现有成员6人,其中博士4人,硕士2人。研究方向为绿色化工与工业催化。主要进行(1)化工生产过程中催化剂的设计、制备、组装和优化研究与(2)工业废水中金属、染料脱除与分离研究。

一、研究内容:

1.化工生产过程中催化剂的设计、制备、组装和优化,开展催化机理、绿色催化过程开发与应用研究。聚焦尼龙化工生产过程中苯加氢为环己烯、环己烯水合为环己醇、环己烷氧化为环己酮等不同反应过程中的催化剂的设计、制备、组装和优化研究,赋予其高的催化活性,开展催化机理、绿色催化过程开发与应用研究。

2. 以工业废水、固体废弃物浸出液、盐湖、海洋为研究对象,应用物理化学、分析化学、化学工程、材料设计等理论和方法,开展战略金属,如锂、钴、铜等分离及利用的科学问题、关键材料技术研究,为资源有效开发与环境综合治理提供科学依据。

二、团队代表性成果:

1. 科研项目:

1) 国家自然科学基金委员会, 面上项目, 21676280, 离子液体-钛配合物协同催化烯烃三聚反应新过程, 2017-01-01 至 2020-12-31, 64万元, 结题, 参与.

2)国家自然科学基金委员会, 联合基金项目, U1662133, 烯烃与CO2羰基酯化反应的非贵金属催化剂及过程调控研究, 2017-01-01 至 2019-12-31, 65万元, 结题, 参与.

3) 国家自然科学基金委员会,联合基金项目,U20A20149,基于预脱镁强化反应分离的盐湖镁锂资源高效提取利用,2021-01-01至2024-12-31,260万元,参与.

4) 国家自然科学基金委员会,面上项目,21978302,离子液体微环境强化盐湖锂在两相介质界面处的分离机制,2020-01-01至2023-12-31,65万元,参与.

5)河南省科技攻关项目,222102230045,离子液体-杂多酸协同精准催化氧化环己烷绿色新过程,2022-01-01至2024-12-31,在研,2万元,主持.

6)河南省科技攻关项目,202102210249,杂多酸型离子液体光催化氧化木质素的研究(科技攻关),2021-01-01至2021-06-30,结题,2万元,主持.

7)河南省高校青年骨干教师资助计划,2015GGJS-257,甲壳素改性制备及其在工业废水中的吸附性能研究,2015.10-2018.10,结题,4.8万元,主持.

8)环己酮装置所用消泡剂的开发应用(横向项目,30万元),主持.

 

9)有机化合物的金属缓蚀性能研究(横向项目,30万元),主持.

10)磁性复合光催化材料的合成及快速降解氮氧化物的性能研究(横向项目),参与.

2. 高水平论文:

1) Yun-Li Cao; Lei Wang; Yin-Ge Bai; Rui-Yi Yan; Bao-Hua Xu ; Molybdovanadophosphoric Heteropolyacid-Catalyzed Aerobic Oxidation of Methacrolein: The Crucial Role of Ionic Liquid as a Modifier, Catalysis LettersSCI, 3区,IF=3.186, 2020.春, x(x): 1-12.

2)Qing-xiang Shi,Yan Li, Li Wang, Jia Wang, Yun-li Cao*, Preparation of supported chitosan adsorbent with high adsorption capacity for Titan Yellow removal, International Journal of Biological Macromolecules, (SCI, 1区, IF=6.953),2020, 152, 440–455.

3)Yun-Li Cao, Lei Wang, Bao-Hua Xu, Suo-Jiang Zhang,The Chitin/Keggin-type Heteropolyacid Hybrid Microspheres as Catalyst for Oxidation of Methacrolein to Methacrylic Acid,Chemical Engineering Journal(SCI, 1区top期刊,IF=6.216),2018, 334,1657-1667. 

4) Yun-Li Cao, Lei Wang, Li-Long Zhou, Guang-Jin Zhang, Bao-Hua Xu, and Suo-Jiang Zhang, Cs(NH4)xH3-xPMo11VO40 Catalyzed Selective Oxidation of Methacrolein to Methacrylic Acid: Effects of NH4+ on the Structure and Catalytic Activity,Industrial & Engineering Chemistry Research(SCI, 2区top期刊, IF=2.843)2017, 56 (3), 653–664.

5) Yun-Li Cao, Lei Wang, Li-Long Zhou, Bao-Hua Xu, Yan-Yan Diao, Suo-Jiang Zhang,A Modified Heteropoly Acid Catalyst with Cetyltrimethylammonium Bromide for Methacrolein to Methacrylic Acid(Accepted),Journal of Industrial and Engineering Chemistry(SCI 2区, IF=4.421).

6) Yun-Li Cao, Zi-Hong Pan, Qing-Xiang Shi, Jun-Ying Yu,Modification of chitin with high adsorption capacity for methylene blue removal,International Journal of Biological Macromolecules(SCI 2区, IF=3.671),2018, 114, 392–399.

7)Bai, Ruibing; Wang, Junfeng; Wang, Daoguang; Zhang, Yanqiang; Cui, Junjie ; Selective sep aration of lithium from the high magnesium brine by the extraction system containing phosphate-ba sed ionic liquids, Separation and Purification Technology(SCI 1区, IF=7.312, 2021, 274: 119051.

8) Bai, Ruibing; Wang, Junfeng; Cui, Li; Yang, Shicheng; Qian, Wei; Cui, Penglei; Zhang, Yan qiang ; Efficient Extraction of Lithium Ions from High Mg/Li Ratio Brine through the Synergy of T BP and Hydroxyl Functional Ionic Liquids, Chinese Journal of Chemistry(SCI 3区, IF=6.000, 2020, 38(12): 1743-1751 .

9) 白瑞兵; 王均凤; 王道广; 张延强 ; 离子液体基萃取体系用于卤水中锂分离的研究进展, 化工进展, 2021, 40(6): 3224-3238.

10) Wang, Junfeng; Yang, Shicheng; Bai, Ruibing; Chen, Yongmei; Zhang, Suojiang ; Lithium rec overy from the mother liquor obtained in the process of Li2CO3 production, Industrial & Engineeri ng Chemistry Research SCI 2区, IF=3.534, 2019, 58: 1372.

11)Yibo Wu, Fuxiang Li*, Jianwei Xue, Zhiping Lv. Sn-imidazolates supported on boron and nitrogen-doped activated carbon as novel catalysts for acetylene hydrochlorination. Chemical Engineering Communications, 2019: 1-13.

12)Yibo Wu, Longjie Cui, Rong Zhang, Rujing Pei, Sufang Hu, Ruyue Han, Hupin Yang, Fuxiang Li*, Jianwei Xue, Zhiping Lv, PhnSnCl4-n supported on activated carbon as novel tin-based catalysts for acetylene hydrochlorination. Química Nova, 2019, 42(7): 752-759.

13)Yibo Wu, Fuxiang Li*, Zhiping Lv, Jianwei Xue, Synthesis and characterization of X-MOF/AC (X= tin or copper) catalysts for the acetylene hydrochlorination. ChemistrySelect, 2019, 4(32): 9403-9409.

14)Yibo Wu, Fuxiang Li*, Zhiping Lv, Jianwei Xue, Carbon-supported binary Li-Sn catalyst for acetylene hydrochlorination. Journal of Saudi Chemical Society, 2019,23(8):1219-12.

15)Yibo Wu, Fuxiang Li*, Jianwei Xue, Zhiping Lv. Effect of various g-C3N4 precursors on the catalytic performance of alkylorganotin-based catalysts in acetylene hydrochlorination[J]. Turkish Journal of Chemistry, 2020, 44(2):393-408.

16)Yibo Wu, Yang Ma, Qingbin Li, Songtian Li, Yongjun Han, Fuxiang Li*. Carbon-supported copper-organic framework as active catalysts for acetylene hydrochlorination[J]. Canadian Journal of Chemistry, 2021,99(10):812-820.

17)Yibo Wu, Fuxiang Li* Guoqiang Song, Yunli Cao, Fu Xv, Zihong Pan, Yangyang Feng, Qingbin Li. Effect of -COOH in organic linkers on the hydrochlorination performance of SnMOF-based catalysts [J] Journal of the Chinese Chemical Society. 2021,68(11):2151-2163.

18)Yibo Wu, Fuxiang Li*, Xiaoqiang Luo, Gang Tian, Yunxiao Feng, Yongjun Han, Li Wang, Songmao Chu, Yunli Cao, Kesheng Cao, Xiaoming Hu, Xuejun Shi, Songtian Li, Guoxv He, Qingbin Li. Tin-sulfur based catalysts for acetylene hydrochlorination[J]. Turkish Journal of Chemistry, 2021, 45(3): 566-576.

3. 专利:

1)一种水热法制备的磷钼钒酸类纳米催化剂,CN107297216B(已授权)

2) 一 种 负 载 含 氯 有 机 锡 和 含 氮 化 合 物 的 催 化 剂 及 其 制 备 方 法 和 应 用,201710696202.8 (已授权)

3)一种输电设备,CN109709444 B(已授权)

 

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